1. You cannot "intend" to "reside" in Quebec using FSW. If you do, you have to use the Quebec provincial immigration process.
2. Wherever you do land, you cannot declare your intention to "reside" in Quebec either, if you do, [I am not sure exactly what happens]. But you cant.
3. After you "land" in anywhere in Canada declaring your intention to reside in any part of Canada other than Quebec, you can move to and live anywhere in Canada, including Quebec, as the Canadian Charter of Freedom provides freedom of movement. Residents of Canada are protected by the CoF.
However, remember, the law works on "intention." If there is ever a question on your immigration status, and they are able to prove that you always had the intention of residing in Quebec, but you stated otherwise during your immigration process, then they can prosecute you for material misrepresentation of fact, which can lead to cancellation of your PR. How you overcome this is a question of law and fact and you should rely on an attorney. It can be overcome though.