This is the wrong section of the forum for this question.
For questions about your spouse's ability to obtain an open work permit, post to the Foreign Workers section of the forum.
If you are interested in applying for PR, then you'll need to research Canada's various immigration programs to see what the requirements are and if you qualify. I would recommend you start with the Express Entry program which is a points-based program. Those with the highest points who are in the pool are selected for PR. Right now you need a score of around 500 to be selected. So calculating your score will tell you what your chances are under this program. You should also check out Quebec's programs since that's where you'll be living and working. Express Entry program details are here:
https://www.canada.ca/en/immigration-refugees-citizenship/services/immigrate-canada/express-entry/works.html