please refer.
To submit an official immigration application, you must fill out:
the Application for Selection Certificate – Skilled Worker – Principal applicant, spouse or de facto spouse (A-0520-AA) (Dynamic PDF 687 Kb);
the Documents to submit in support of the
Application for a Certificat de sélection du Québec – Skilled Workers (regular program) (Dynamic PDF, 682 Kb). Don't forget to consult the List of authorities recognized for certifying documents .
Note: The Ministère applies rules concerning
document requirements. These requirements pertain to the nature, format and, if applicable, the translation of documents to be submitted.