If your employment is accepted, you will meet the RO and your wife too as your spouse accompanying you. However, as others have said, immigration is strict in regards to who is considered a Canadian employer and even how the job came about.
Sometimes employment can be borderline and they might still let you get away with it but there are different scenarios. Say you had lived in Canada almost 2 years, you get that job and get posted overseas, they might be more inclined to let you slip than say if you spent 3 years outside Canada and then arranged a Canadian employer to post you overseas right away. Immigration will see it as a lack of willingness to settle in Canada and and attempt to keep your PR without spending any time here.