Welcome ..
The originals must always be your IELTS result and ECA report.Your police clearance certificate should also be original.
The other documents can be in photocopies unless ofcourse you feel it's not useful...e.g statement of account and/or reference letter .I'm sure you can't afford to submit the rest documents in original .
I'll prefer you include photocopies of your employment letter and payslips also to strengthen your reference letter.
Also,you do not need stamped envelopes......you need self addressed mail labels.This can simply be achieved by using a Microsoft word document on your laptop to write your full names and address on half of the page.Then duplicate it on the other half of the page after which it's printed out.Cut it into 2 nd insert into your package.
Since you are submitting biodata pages of both your old and new passport document,include a short cover letter to explain reason for such .
Your passport photographs are meant to be 6 for one person.......at the back of 5,write your full names,date of birth and date when picture was taken while you leave one blank.
Be wary of your birth certificate ......make sure it's authentic and accepted.
Make sure that you include the photocopies of the certificates/degree from your school that was used for your ECA report.
If possible ,let someone help you to check the correctness of your forms you intend to submit.....also,make sure u use the current form on CIC website.
Finally ,endeavor to use demand draft as your mode of processing charge .
Wishing you the best.
Cheers.
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You should also notarise the photocopies please.