Mugwump said:
If I do decide to go another route does this raise red flags for CIC? I've read here that N.S. is looking for educators with advanced degrees and considered applying that way. What are my chances that this situation negatively affects my second application?
If you're clear about the situation, it shouldn't affect your application in any way - rather the contrary. You could just say that you had applied for spousal sponsorship and was granted PR, but your marriage broke down, and you decided not to land as a PR and apply on your own. It would show that you are prepared to get to Canada, but in a legal way.
I know that NS has recently started a new program where you need to be on the list of jobs/professions that are needed, but you don't need a job offer necessarily. see here http://novascotiaimmigration.com/immigrate/regional-labour-market-demand/
it's a new program, and it's in the beginning phase, so you might not be able to get in right away, but it's a more secure way to go - if you decide to land as a PR now based on the spousal sponsorship, you risk :
1) either to be turned back at the border on arrival if your wife has reported you
2) to have your PR taken away at any point if your wife reports you in the next few years
Neither of these are good options. Look at various immigration streams, find one that will suit you, and come to Canada on your own.
Sweden