I don't know what the requirements are for the various PNP programs.
For EE/FSW, any skilled work experience in the last 10 years counts towards the minimum requirements and the points.
Here are the requirements - you will notice it does not state anything about a requirement to be employed presently:
"Skilled work experience
- Managerial jobs (skill type 0)
- Professional jobs (skill level A)
- Technical jobs and skilled trades (skill level B)
You must show that while working in your primary occupation, you performed the duties set out in the lead statement of the occupational description in the NOC. This includes all the essential duties and most of the main duties listed.
Your skilled work experience must be
- in the same type of job (have the same NOC) as the job you want to use for your immigration application (called your primary occupation)
- within the last 10 years
- paid work (have been paid wages or earned commission—volunteer work or this means you must unpaid internships don’t count)
- at least 1 year of continuous workor 1,560 hours total (30 hours per week)—you can meet this in a few different ways:
- Full-time at 1 job: 30 hours/week for 12 months = 1 year full time (1,560 hours)
- Equal amount in part-time: 15 hours/week for 24 months = 1 year full time (1,560 hours)
- Full-time at more than 1 job: 30 hours/week for 12 months at more than 1 job = 1 year full time (1,560 hours)"
If your wife meets the requirements above, she will qualify. Simple as that.
There is no risk that the profile won't be "picked up", as you call it.
The system does not work like this. Any candidate with the required amount of CRS points will receive an invitation to apply.