Dear Heck,
Please share your timelines. You can write a letter and post to NDVO directly and mention your situation that you have got the acceptance from University of Toronto.
If you are at 3rd Line stage than request for PPR.
Or If you awaiting 2nd Line then go for up front medical , pay RPRF and send E-medical information sheet, RPRF, Letter from university and your application for expediting the PR.
Above process was followed by forum member and he has got mapple leaf stamped.
You can update your timelines by clicking profile -> Forum Profile Information. so that people can guide you accordingly.
All the best. It seems that priority is given to students over FSW