You can apply under Arrange Employment Section. Its written there in guide too. If you have any job offer or something from Canada. You can apply.
see,
According to the Minister’s instructions, your application is eligible for processing if:
* you have an offer of arranged employment, OR
* you are a foreign national who has been living legally in Canada for one year as a temporary foreign worker or an international student, OR
* you are a skilled worker who has at least one year of experience in one or more of the occupations listed here.
Regards,
Jawad...