- Yes I am 100% sure you'll receive a NOI IF you currently employed or have a job offer by/form an Ontario employer; so even if it's not LMIA supported you're good. Once you fill in the EE profile, it's gonna ask you several questions related to the job itself (ie location, start date, end date, level, etc). Section " Intended work in Canada" will ask you if you have a job offer, answer "Yes" and it will show up a new window asking for further fields including (start/end, location, job title, level, LMIA or not.. etc).
- Yes, after you finish with OINP (which takes 4-6 months anyways!) you'll be eligible for the additional 600 points (only then you'll receive ITA from EE). Long process compared to direct ITA from EE, however, some people cannot (or will not) fulfil the 440+ points CRS so NOI from provinces is their only choice. OINP Steps are outlined here:
http://www.ontarioimmigration.ca/en/pnp/OI_PNP_EE_CAPITAL_HOW.html
Hope this helps!