Also, I have one more question.Not sure what you mean by pending. She will have implied status. If the LMIA is approved in time and the work permit is approved, no issues. If the LMIA is not approved in time or if the LMIA is refused, the application will most likely be rejected (due to not having an approved LMIA) which will then put her out of status in Canada effective the day her current work permit expired.
I understand that for EE, the job offer has to be valid for 1 year after becoming a PR . But if her employer is willing to give a permanent job offer, could she directly apply for OINP? She has gathered 2 years of Canadian Experience so far.
If eligible to apply, would applying for PNP allow her to work in any way?