yes u can apply for pr to canada on that basis. chef and cooks are in the list of 38 jobs for ministerial instructions.all u need is to calcultae ur points on the basis of english proficiency, education, work experience and ur adaptability.
check out this list, it shows cook and chef as code 6241 and 6242.
http://www.cic.gc.ca/english/immigrate/skilled/apply-who-instructions.asp
try to use this tool and calculate ur point it will help u to know if u get 67 pass marks
http://www.cic.gc.ca/english/immigrate/skilled/assess/index.asp
good luck . email me for further queries. anyway where u from and wats ur work experience