LOL, I have no idea what a "time served joiner" is! Your eligibility all hinges on your/your husband's work experience. You would have to see if you meet the minimum of 67 pts under the Federal Skilled Workers program, as well as the criteria for express entry. Which ever of you have the most skilled work experience should be the Principal Applicant.
You need to identify the NOC Code for all your primary occupations as well as work experience. Use the CIC tool to determine your eligibility.
http://www.cic.gc.ca/english/immigrate/eligibility.asp
If you determine that you are eligible, it will take time to gather all the documentation you need to apply. For the FSW program, the PA needs letters of employment for all skilled work in the past 10 years. And I realize that your first language is English, but one or both of you will need to take an exam to prove your language competence - it's mandatory for ALL applicants. If either of you also speak French, you can get a few more points by taking that exam as well. If you both take the exam, you'll get more express entry points.
Some of the provincial nominee programs also accept applicants who are not already in Canada, if they are experienced in a high-demand occupation.