An LMIA is basically a document in which your employer confirms that there is nobody else in the whole country be it a Canadian Citizen, Permanent Resident or temporary worker with an open work permit, who can cope with the requirements of such position. They have to back this claim with valid job postings and interview logs of failed candidates. And even after issuing the LMIA they will have to keep posting the job opening and if a Canadian or PR with the right credentials shows, he will take your place.
As an example a Mcdonalds, Tim Horton, or any other fast food franchise won't be able to hire you, since it will be very difficult for them to prove that there are no Canadians or PR unable to make a burger and french fries. On the other hand If for your occupation is related to a very specific niche like a software tool like IBM Cognos or MatLab, you MIGHT get a chance, even when there are many professionals who can do it, there might be a shortage in the market, or within those tools there might be a couple of processes which too little people know.
In order to immigrate to Canada, you need to get at least undergraduate education, since you have a desire to immigrate fast, and you lack an undergrad degree, I strongly suggest you to consider a Canadian an academic institution, even a college will do. There are some options where you can actually get a 2 years degree, some of them with a Co-Op option.
Co-op means that you will be getting a chance to work in a company (some times colleges and universities have Co-ops agreements with big employers) as part of your studies.