PNP Ontario clarification ( without job offer)

[student2016]

Hello Friends,
My name is Ali. I need a clarification about the Ontario PNP:

Does Ontario PNP requires any job offer?
My sister lives in toronto. I want to apply in this province based on my education , language score , age , experience and PNP nomination.

Please send me a proper link for the Ontario PNP without any job offer.
Your replies will be highly appreciated.
Thanks.