I doubt it, they're just more interested if you have enough $, you're not planning on working, you have return ticket, have a place to stay, and not carrying any drugs.
They don't care you have a pending application to live in Canada permanently, they just care that you will abide by your current TRV and leave when you're supposed to, and not overstay.
My wife had a PR application pending when she got her TRV, but the officer didn't care, they just asked her those questions above and let her in.