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Yes, you should do that at the airport during landing procedure at the immigration office. You should tell the officer that you indend to bring/transfer more money soon. He will write the amount down on you form. In this case you will not show that amount in your tax return for the first year...

http://www.cra-arc.gc.ca/benefits/cctb/menu-e.html Child Tax Benefit

You can apply for work permit. it is quite easy to obtain it when you are in Canada in a process of getting PR as a spouse..

And do you have ?

I know a person in the USA who got there a bachelor degree (4 years) and who still was asked to take the IELTS.

Because you are not divorced you can neither marry not to be considered as a common law partner for IMMIGRATION purposes.