+1(514) 937-9445 or Toll-free (Canada & US) +1 (888) 947-9445
This application is for persons who are in Canada on a valid temporary resident permit and wish to apply for permanent residence. Applicants must have lived continuously in Canada as permit holders for a minimum of three to five years (depending on the reason the applicant is inadmissible to Canada under the Act) before they are eligible to apply for permanent residence.

Nope

Correct, , temporary permit holders is different category.
 
Should I pay the fee before applying? And if I am unable to apply in this stream, will I be able to use this money for express entry?